Cross-Coupling Reactions by Cooperative Metal Catalysis

Metal Catalysed Cross-coupling Reactions of Heterocycles

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"Homeopathic" palladium nanoparticle catalysis of cross carbon-carbon coupling reactions.

Catalysis by palladium derivatives is now one of the most important tools in organic synthesis. Whether researchers design palladium nanoparticles (NPs) or nanoparticles occur as palladium complexes decompose, these structures can serve as central precatalysts in common carbon-carbon bond formation. Palladium NPs are also valuable alternatives to molecular catalysts because they do not require ...

Hydroamination reactions by metal triflates: Brønsted acid vs. metal catalysis?

Catalytic hydroamination reactions involving the addition of carboxamides (X = CO), carbamates (X = CO(2)) and sulfonamides (X = SO(2)) to unactivated C=C bonds are briefly reviewed. Development in this field of catalytic research is briefly charted, followed by a discussion of possible mechanisms, including arguments to support the operation of both metal and Brønsted acid catalysis in these s...

The Metal-Catalyzed Cross-Coupling Reactions of n-Butylketene Dimer

Alkylboron Cross-Coupling Reactions

The ability to append alkyl moieties onto preexisting molecular scaffolds is of significant interest owing to the breadth of the diversified compounds that can be accessed in late stage synthesis. There are a number of procedures that are capable of incorporating alkyl subunits into organic molecules; however, many of these strategies are limited in scope. In particular, the highly reactive nat...